CATALYTIC PYROLYSIS OF DISCARDED COVID-19 MASKS OVER SEPIOLITE

This research aims to develop a new strategy to valorize wasted COVID-19 masks based on pyrolysis to convert them into useful products. First, surgical and FFP2 masks were thermally pyrolyzed at temperatures of 450–550 ºC with the purpose of determining gas, liquid (oil) and solid (char) yields. At low temperatures, solid yield was high, while at high temperatures the gas product was enhanced. The highest yield of liquid was found at an operating temperature of 500 ºC in both surgical and FPP2 masks pyrolysis. The liquid product yields were 59.08% and 58.86%, respectively. Then, the volatiles generated during thermal pyrolysis of residual masks were cracked over sepiolite as catalyst at a temperature of 500 ºC. The catalytic pyrolysis increased the yield of gas product (43.89% against 39.52% for surgical masks and 50.53% against 39.41% for FFP2 masks) and decreased the viscosity of the liquid product. Finally, the effect of sepiolite regeneration and reuse in consecutive pyrolysis tests was examined. Results showed that, with the higher regeneration-reuse of sepiolite, the catalyst was degraded obtaining a liquid product with higher molecular mass. This effect was hardly noticeable in the case of FFP2 masks. © 2022 International Multidisciplinary Scientific Geoconference. All rights reserved.

The energy assessment of COVID-19 medical waste as a potential fuel

The COVID-19 pandemic has caused huge health and economic damages. Various protective face masks, such as single-use, cotton, and the most widespread FFP2 or KN95 masks, are used to prevent the spread of this virus. However, these face masks are usually packaged in plastic packaging, which increases the amount of plastic waste. Plastic gloves are also often used in the connection of the pandemic. All this leads to a large production of protective equipment, but their use contributes to the increase of this type of waste, which presents a new challenge in waste management. This article investigates a complete element analysis of these mentioned materials and observes potential harmful substances. Further, pellets, as a potential fuel for combustion or pyrolysis purposes, were produced with the content of 5% and 10% of face masks. FFP2 were firstly separated from ear straps and wires, then disintegrated, added to spruce sawdust, and compressed into pellets. A series of experiments were realized and aimed at elemental, thermogravimetric, and calorific value analyses of produced pellets. Based on the results, it can be concluded that the presence of face masks FFP2 in pellets increases the content of carbon, hydrogen, and nitrogen, volatile matter, and calorific values, but decreases the content of fixed carbon. According to elemental analysis of produced pellets, no significant amounts of harmful elements were found. © 2023 The Author(s)

A review of plastic pollution and their treatment technology: A circular economy platform by thermochemical pathway

The rapid expansion of plastic manufacturing industries in last several decades has brought serious concerns over the environmental impacts of plastic wastes. Recent outbreak of Covid-19 drastically increased production, use, and disposal of plastic products. Current management strategies for wasted plastics still rely on landfill and incineration that continue to exacerbate plastic pollution and carbon emissions. Many countries have put forward multifaceted administrative efforts to reduce plastic wastes, but the annual global generation of plastic wastes is still increasing. In techno-society, researchers have been exploring more effective plastic wastes treatment technologies to alleviate environmental impacts of plastic wastes. Such efforts entailed several technical options that can potentially contribute to establishing a circular economy for plastics. Thermochemical process is a prominent example of such techniques. This review presents an overview of the issue of plastic pollution, covering topics including global plastic production, environmental impacts, and toxicity. In addition, the global administrative efforts aimed at reducing plastic pollution are discussed, as well as detection and treatment strategies to establish a circular economy in plastic management. © 2023 Elsevier B.V.

Circular Economy and Sustainable Development Goals 3 and 17: The Case of the PlastiCity Ecosystem

Plastic pollution is one of the most severe environmental and human health threats. Based on a linear model, our current economic system uses plastics as a primary resource to make products such as plastic bags and bottles. However, these products are not recycled into secondary resources. Instead, they are thrown away when they become unusable. In contrast, the circular economy considers plastic waste as an opportunity to create social, economic and environmental value. This model uses plastic waste as a raw material to produce new items. This research demonstrates that the circular economy contributes to Sustainable Development Goals 3 and 17 using the results of action and observatory research within the PlastiCity project. As part of PlastiCity, partners developed new products made from recycled plastic such as recycled face shields. This chapter describes our efforts in developing a business case for recycled face shields and deploying the PlastiCity ecosystem to improve collaboration and partnerships. This study suggests that the development of an ecosystem can facilitate collaboration between stakeholders in the plastic value chain and hence contribute to implementing circular business models. This research also demonstrates how the circular economy can respond rapidly to health-related societal challenges, such as the unavailability of personal protective equipment during the COVID-19 pandemic. © 2023, The Author(s), under exclusive license to Springer Nature Switzerland AG.

Packaging plastic waste management in the cosmetic industry

PurposeThis paper aims to explore the relationship between the various variables present in the packaging plastic waste management system in the cosmetics industry.Design/methodology/approachIn this paper, the authors deal with plastic packaging waste in the cosmetic industry with the help of system dynamics. The model broadly divides the system into six sections – Cosmetic Packaging, Waste Generation, Waste Collected, Waste Sorted, Waste Treated and Waste Dumped. Businesses have been investing in each section depending on their progress and targets. The authors are looking at case studies of two leading cosmetic brands, L'Oréal and L'Occitane en Provence, to validate the industry practices against our model.FindingsFrom a business perspective, using the case study methodology for L'Oréal and L'Occitane, the authors inferred that out of the various investment vehicles available, companies are targeting technological advancement and third-party collaborations as they have the potential to offer the greatest visible change. However, most of these investments are going toward the treatment subsection. Still, there is a scope for improvement in the collection and sorting subsystems, increasing the efficiency of the whole chain.Originality/valueThere has been a lot of research on packaging plastic waste management in the past, but only a few of them focused on the cosmetic industry. This study aims to connect all the possible variables involved in the cosmetic industry's packaging plastic waste management system and provide a clear output variable for various businesses looking to manage their packaging waste because of their products efficiently.

Insights on the current status of effective strategies for waste management in COVID-19 pandemic: challenges and opportunities

A large number of people got infected and many lost their lives due to COVID-19. The increased volume and source-shuffling of the waste generated during the pandemic have challenged the current waste management facilities. The major sources of infectious waste not only include hospitals but also houses and quarantine facilities that lack in source-management thereby increasing the spread of the virus. This article focuses on waste collection and disposal techniques as major aspects of COVID-19 waste management. Also, it discusses the various waste disinfection technologies along with waste management strategies formulated by different organisations. The non-pharmaceutical intervention strategies have also been identified. Alongside this, various challenges and opportunities in COVID-19 waste management are reviewed. Accordingly, recommendations to achieve efficient waste management are stated. Waste management in case of such a pandemic requires proper segregation, storage, collection and treatment. Usage of multiple processes like pyrolysis, chemical treatment, microwave and radio wave is needed to be found for treatment of infectious waste. Increased amount of mixed waste creates the need to have method that is flexible enough. Large amount of PPE waste needs to be taken care of. Development of materials that can provide hygiene and have recyclability is essential. © 2023 Indian Institute of Chemical Engineers.

Photoredox-Catalyzed Plastic Waste Conversion: Nonselective Degradation versus Selective Synthesis

Plastic waste pollution is becoming one of the most pressing environmental crises due to the large-scale production without satisfactory recycling schemes, especially with the outbreak of the COVID-19 pandemic in recent years. Upcycling of plastic waste into valuable chemicals powered by solar energy presents a substantially untapped opportunity to turn waste into treasure. In this review, the fundamental principles from plastic nonselective degradation to selective synthesis are first clarified. Then, we aim to outline the representative recent advances in photoredox-based catalytic plastic waste conversion. Particular emphasis is placed on the valorization of plastic waste regarding nonselective degradation versus selective synthesis. Finally, we present challenges and individual insights for further exploration of the plastic waste conversion domain. It is anticipated that this timely and critical review would provide an instructive direction and foresight on the selective conversion of plastics to value-added chemical feedstocks, thus stimulating the development of a circular and sustainable plastic economy in the coming decades. © 2023 American Chemical Society.

Plastic waste management and safety disinfection processes for reduced the COVID-19 Hazards

In response to the pandemic of COVID-19, various unexpected environmental impacts in many countries have been rising. Millions of gloves and masks are used and thrown away daily around the globe. Incorrect disposal of COVID-19 waste without disinfection preparation could expose people and healthcare personnel to the possibility of spreading the infection of coronaviruses. This article finds an appropriate way to disinfect the waste of coronavirus-infected items by involving various physical factors, chemical and biological or physiological factors. Policymakers must immediately adopt disinfection technology to achieve green recovery of covid-19 waste that encourages development and sustains climate change. Regarding previously published papers and research results, this article intends to investigate the plastic pollution research status before and during the COVID-19 pandemic and outline safely disinfecting COVID-19 plastic waste. © 2023 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group.

Upcycling disposable face masks into fuel range iso-alkanes through hydropyrolysis coupled with vapor-phase hydrocracking

The COVID-19 pandemic has resulted in an alarming accumulation of plastic waste. Herein, an integrated hydropyrolysis and hydrocracking process was performed to upcycle disposable masks into fuel-range iso-alkanes over carbon supported ruthenium (Ru/C). Experimental results indicated that catalyst type significantly affected product distribution during the hydropyrolysis and vapor-phase hydrocracking of disposable masks. Compared with zeolites-induced catalytic cascade process where up to ∼25.9 wt% yield of aromatic hydrocarbons such as toluene and xylenes were generated, a ∼82.7 wt% yield of desirable iso-alkanes with a high C5–C12 gasoline selectivity of 95.5% was obtained over Ru/C under 550 °C hydropyrolysis temperature and 300 °C hydrocracking temperature at 0.2 MPa H2. The cascade hydropyrolysis and hydrocracking process also exhibited high adaptability and flexibility in upcycling single-use syringes, food packaging, and plastic bags, generating 79.1, 81.6, and 80.3 wt% yields of fuel range iso/n-alkanes, respectively. This catalytic cascade hydrotreating process provides an efficient and effective approach to convert pandemic-derived plastic waste into gasoline-range fuel products. © 2022 Elsevier Ltd

Microplastics in the Ecosystem: An Overview on Detection, Removal, Toxicity Assessment, and Control Release

In recent decades, the accumulation and fragmentation of plastics on the surface of the planet have caused several long-term climatic and health risks. Plastic materials, specifically microplastics (MPs;sizes < 5 mm), have gained significant interest in the global scientific fraternity due to their bioaccumulation, non-biodegradability, and ecotoxicological effects on living organisms. This study explains how microplastics are generated, transported, and disposed of in the environment based on their sources and physicochemical properties. Additionally, the study also examines the impact of COVID-19 on global plastic waste production. The physical and chemical techniques such as SEM-EDX, PLM, FTIR, Raman, TG-DSC, and GC-MS that are employed for the quantification and identification of MPs are discussed. This paper provides insight into conventional and advanced methods applied for microplastic removal from aquatic systems. The finding of this review helps to gain a deeper understanding of research on the toxicity of microplastics on humans, aquatic organisms, and soil ecosystems. Further, the efforts and measures that have been enforced globally to combat MP waste have been highlighted and need to be explored to reduce its potential risk in the future. © 2022 by the authors.

A comprehensive review on the production of alternative fuel through medical plastic waste

This paper aims to critically review the production of alternative fuels through medical plastic waste. In the recent past, medical plastic waste has been disposed of and incinerated in the dumping yards, which is the main cause of the threat of infection and environmental hazards. Adopting proper waste management and the appropriate technology like the 5R's (refuse, reduce, reuse, repurpose, and recycle) may significantly improve the ecosystem. Moreover, the 5R's is a comprehensive approach that can be applied, either awareness of stakeholders or enforcement mandate and regulation by the government. The current review suggested the possible route for converting medical-plastic waste into drop-in fuel and value-added products to minimize the waste through suitable technology. In this, the pyrolysis technique plays an important role which is more ecologically friendly, effective and produces minimal pollutants. It has been observed that using COVID medical waste management (CMWM) technology, 70–80 % plastic pyrolysis oil (PPO), 10–15% bio-char, and gaseous fuel can be extracted. As per the ASTM, the extracted PPO is a potential feedstock for the CI engine fuel. This review work provides a suitable solution for CMWM and improves the quality of medical infrastructure for sanitation in a sustainable mode. © 2022 Elsevier Ltd

Analysis of Trends and Challenges of a Worldwide Solid Waste Management with Emphasis on Covid-19 Pandemic-A Review

Low collection coverage, lack of a safe and appropriate destination for all generated waste and pollution caused by inadequate waste disposal procedures are probably one of the most significant threats in the current decade (2021-2030). At the beginning of 2020, a new and unforeseen challenge emerged-the COVID-19 pandemic. This article provides a brief overview of the state of waste management in the world, identifying significant challenges that arose during the pandemic. As the situation changed daily in all regions of the world, many local authorities were obliged to react urgently and adjust the current way of waste management. People's habits have changed and the mandatory wearing of protective masks has increased the daily amount of plastic waste worldwide by approximately 21 000+ tons. This represented an additional burden for already under capacitated waste management systems. Also, waste collected from households in many parts of the world had to be treated as medical waste due to the COVID-19 positive people. There was a drastic increase in the daily amount of generated medical waste due to this, which in some cases was up to 6 times higher than usual. © 2022, Strojarski Facultet. All rights reserved.

Current Progress in Thermochemical Conversion of Plastics into Jet-fuel Hydrocarbons and Recommendations for COVID-19 Waste Management

A vast amount of plastics are produced globally to comply with human needs. Additionally, the COVID-19 pandemic enabled an extreme rise in single-use plastic, creating an extra burden on plastic waste handling and promoting environmental pollution. Thermochemical conversion of plastic wastes into liquid hydrocarbons would be promising in this context. Numerous literature showed plastic-to-liquid hydrocarbon fuel formation;however, jet-fuel grade hydrocarbons generation from plastics is rarely assembled and hence become the focus of the current review. Reportedly, 200 – 600 °C reaction temperature, 10bar hydrogen pressure, 12 hrs retention time, and 0.13 catalyst-to-feed ratio produced jet fuel from plastics;albeit, it remained system-specific, including batch and continuous processes. Critical evaluation of several plastics to jet-fuel techniques suggested research attention in (i) complete plastic conversion into the plastic-derived oil, (ii) catalyst selection and new design enabling aliphatic/aromatics selectivity within the product mixture, (iii) mechanistic understanding of plastic to jet-fuel processes (with and without catalyst), and (iv) catalyst recyclability studies. Thermal degradation under microwave, hydrothermal liquefaction, pyrolysis, methanolysis/hydrogenation, thermal cracking/co‑hydrogenation, and aqueous phase hydrodeoxygenation are possible routes for plastic to jet-fuel conversion. Catalytic pyrolysis could be a promising for plastic/COVID-19 thermochemical conversion into jet fuel, and biomass-derived catalysts may replace the expensive metal-based catalysts.

Plastic Waste Management towards Energy Recovery during the COVID-19 Pandemic: The Example of Protective Face Mask Pyrolysis

This paper presents an assessment of the impact of the COVID-19 pandemic on the waste management sector, and then, based on laboratory tests and computer calculations, indicates how to effectively manage selected waste generated during the pandemic. Elemental compositions—namely, C, H, N, S, Cl, and O—were determined as part of the laboratory tests, and the pyrolysis processes of the above wastes were analysed using the TGA technique. The calculations were performed for a pilot pyrolysis reactor with a continuous flow of 240 kg/h in the temperature range of 400–900◦ C. The implemented calculation model was experimentally verified for the conditions of the refuse-derived fuel (RDF) pyrolysis process. As a result of the laboratory tests and computer simulations, comprehensive knowledge was obtained about the pyrolysis of protective masks, with particular emphasis on the gaseous products of this process. The high calorific value of the pyrolysis gas, amounting to approx. 47.7 MJ/m3, encourages the management of plastic waste towards energy recovery. The proposed approach may be helpful in the initial assessment of the possibility of using energy from waste, depending on its elemental composition, as well as in the assessment of the environmental effects. © 2022 by the authors. Licensee MDPI, Basel, Switzerland.

Potential Impact of the Covid-19 Pandemic on Plastic Medical Waste Management in South Africa: A Narrative Review

The global increase in plastic consumption has intensified during the Covid-19 pandemic. This review aims to highlight the potential impact of inadequate capacity for medical waste management during the pandemic phase, assess existing capacity in South Africa, and discuss the way forward. Key findings are;mismanaged medical waste can result in the secondary transmission of diseases and medical waste capacity can undoubtedly be compromised by outbreaks of diseases. South Africa is at a vantage point where it can learn from other countries such as China whose pre-Covid-19 capacities were overwhelmed by the surge in medical waste. With around 34.1% of households lacking waste collection services, the current medical waste management systems may not be fully adequate to handle the expected increase in waste as Covid-19 infections rise. To prevent challenges associated with poor waste management practices;as resources are channeled towards containing the Covid-19 pandemic, equal effort should also be directed towards increasing the country's medical waste management capacity including transportation services and labour. A full audit of the systems across the country is required. Existing infrastructure that can be utilized, including cement kilns and furnaces, should be identified, while mobile incinerators will also be advantageous. © 2021 IEEE.

Quantification and mapping of domestic plastic waste using GIS/GPS approach at the city of Guayaquil

A significant contributor to the waste stream is the domestic single-use plastic used in households, being the final disposal in most cases the local landfill. There is a significant opportunity to promote resource recovery and efficiency through the introduction of circular economy strategies. However, the knowledge and management of post-consumer plastic waste in the country is poor, and there is a lack of an efficient collection and sorting system. In this context, spatial information on domestic plastic waste generation (DPWG) is essential for recycling decision-making. The integration of Geographic Information Systems (GIS) and the Global Positioning System (GPS) shows an opportunity to collect, mapping, and analyse spatial DPWG issues. Thus, this paper had a double objective. The first was to assess the evolution of eight different types of plastic waste in the city's households and their daily per capita generation between 2019 and 2021. The second objective was to provide a complete geo-referenced information on the quantities and typologies of domestic plastic waste (DPW) produced in Guayaquil and analyse how the flows have shifted throughout the years. The results showed that PET is the most generated, recording 97.76% and 100.00 % of the households who generate this type of plastic for 2019 and 2021, respectively, with an average of 13.08 and 15.13 g/day/c. Following, we had HDPE, PP and PVC occupying the second, third and fourth place for 2019 with 5.86, 3.05, 2.54 g/day/c, respectively. On the other hand, for 2021, PP (7.43 g/day/c), HDPE (5.92 g/day/c), and LDPE (3.99 g/day/c) occupied the second, third and fourth, respectively. According to the spatial maps, the DPW increment is in most of the popular zones. These popular zones are neighborhoods with a considerable quantity of population and limited basic services. Most of these people live in extreme poverty, being a possible relation between the COVID-19 lockdown and the increasement of DPW. © 2022 Elsevier B.V.. All rights reserved.

Design and Modeling of Shredding Machine for Recycling Plastic Waste

Coronavirus disease (COVID-19) pandemic affects plastic waste management all over the world. Plastic wastes from the medical field, such as surgical masks and personal protective equipment are massively dumped and affected human health and environmental. There are several strategies to improve medical plastic waste management, one of them is to do recycling. A plastic shredder is a machine used for cutting plastics into smaller parts called granules or pellets. The focus of this paper is to design a shredding machine used for recycling plastic waste. The outcome of this shredding machine can be used for subsequent plastic processing machines such as extrusion and injection machines. The proposed design is prepared using 3D computer-aided design (CAD) software and uses several sources on the market to make improvements. This paper covers the design, material used, and strength analysis of the machine. © 2021 IEEE.